Polyether_Polyether Polyol Knowledge 4-Chlorophenyl phenyl sulfone 4-Chlorophenyl Phenyl Sulfone

4-Chlorophenyl phenyl sulfone 4-Chlorophenyl Phenyl Sulfone

4-Chlorophenylphenyl sulfone structural formula

Structural formula

Business number 01QD
Molecular formula C12H9O2SCl
Molecular weight 252.72
label

miticide sulfone,

chlorophenylsulfone,

1-Chloro-4-(phenylsulfonyl)benzene,

Sulfenon,

Trifenson,

1-Chloro-4-(phenylsulfonyl)benzene,

Acaricide

Numbering system

CAS number:80-00-2

MDL number:MFCD00007549

EINECS number:201-242-1

RTECS number:WR5775000

BRN number:None

PubChem number:24851631

Physical property data

1. Properties: Colorless crystals with aromatic smell.

2. Density (g/mL, 25/4℃): Uncertain

3. Relative vapor density (g/mL, air=1): Uncertain

4. Melting point (ºC): 94℃

5. Boiling point (ºC, normal pressure): Uncertain

6. Boiling point (ºC, 5.2kPa): Uncertain Confirm

7. Refractive index: Uncertain

8. Flash point (ºC): Uncertain

9. Specific rotation (º): Uncertain

10. Autoignition point or ignition temperature (ºC): Uncertain

11. Vapor pressure (kPa, 25ºC): Uncertain

12. Saturation Vapor pressure (kPa, 60ºC): Uncertain

13. Heat of combustion (KJ/mol): Uncertain

14. Critical temperature (ºC): Uncertain

15. Critical pressure (KPa): Uncertain

16. Log value of oil-water (octanol/water) partition coefficient: Uncertain

17. Explosion upper limit (% , V/V): Uncertain

18. Lower explosion limit (%, V/V): Uncertain

19. Solubility: This product dissolves in 100ml of solvent at 20°C Grams: acetone 74.4g, benzene 44.4g, toluene 29.4g, carbon tetrachloride 4.9g, insoluble in water.

Toxicological data

Rat caliber LD50: 1400mg/kg; rat abdominal cavity LD50: 500mg/kg;

Mouse caliber LD50: 2700mg/kg; mouse abdominal cavity LD50: 1mg/kg;

Rabbit skin LD50: >1mg/kg;

2. Other multiple dose toxicity data

Dog TDL0: 9mg/kg/15W-I;

Ecological data

None yet

Molecular structure data

1. Molar refractive index: 65.10

2. Molar volume (cm3/mol): 189.7

3. Isotonic specific volume (90.2K ): 494.2

4. Surface tension (dyne/cm): 46.0

5.   Polarizability (10-24cm3): 25.81

Compute chemical data

1. Reference value for hydrophobic parameter calculation (XlogP): None

2. Number of hydrogen bond donors: 0

3. Number of hydrogen bond acceptors: 2

4. Number of rotatable chemical bonds: 2

5. Number of tautomers: none

6. Topological molecule polar surface area 42.5

7. Number of heavy atoms: 16

8. Surface charge: 0

9. Complexity: 306

10. Number of isotope atoms: 0

11. Determine the number of atomic stereocenters: 0

12. Uncertain number of atomic stereocenters: 0

13. Determine the number of chemical bond stereocenters: 0

14. Number of uncertain chemical bond stereocenters: 0

15. Number of covalent bond units: 1

Properties and stability

Irritating to eyes, skin and respiratory tract. Production equipment must be sealed and operators should wear labor protection supplies. Maintain good ventilation in the workshop.

Storage method

1. This product is toxic and is packed in plastic-lined barrels. Protect from moisture, heat and sun, and store in a cool, ventilated and dry place.

2. Store and transport according to the regulations on toxic chemicals.

Synthesis method

1. Obtained from chlorosulfonation and condensation of p-chlorobenzene sulfonic acid. 1. Stir and react dry p-chlorobenzenesulfonic acid and chlorosulfonic acid at 55-60°C for 1.5-2h. The reactants were added dropwise to cold water, and water precipitation was carried out at 25-35°C. Filter the precipitated product to obtain p-chlorobenzenesulfonyl chloride wet product. Heat the wet product to 55-60°C to melt and let it stand to separate out p-chlorobenzenesulfonyl chloride with a content of more than 96%. 2. Condensation: Add molten p-chlorobenzenesulfonyl chloride to the condensation pot, add aluminum trichloride, add benzene dropwise at 60-70°C, complete the addition, and react at 90-95°C for 1 hour. Add the condensation liquid to 3-4% dilute hydrochloric acid for water precipitation, filter, wash with water until neutral, and dry to obtain a product with a content of 95%. Raw material consumption quota: p-chlorobenzenesulfonic acid (92%) 1200kg/t, chlorosulfonic acid 1250kg/t, benzene 355kg/t.

Purpose

Effective against adult mites and mite eggs. It can prevent and control various mites in cotton, fruit trees, vegetables and other crops. It is also good against bee parasitic mites. The prevention and control effect. The usage concentration is 0.09%. Effective on both adult mites and mite eggs. Acaricides are less effective against pests.

This article is from the Internet, does not represent the position of Toluene diisocyanate reproduced please specify the source.https://www.polyether-factory.com/archives/14383

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