Polyether_Polyether Polyol Knowledge Glycine Anhydride Glycine Anhydride

Glycine Anhydride Glycine Anhydride

Glycine anhydride structural formula

Structural formula

Business number 02TT
Molecular formula C4H6N2O2
Molecular weight 114.10
label

2,5-piperazinedione,

Glycine anhydride,

Anhydrous glycidyl amino acid diazacyclodione,

2,5-diketopiperazine,

2,5-Dioxypiperazine,

p-diazacyclodione,

diketopiperazine,

Anhydrous glycine,

Piperazine-2,5-dione,

2,5-Dioxopiperazin,

2,5-Dioxopiperazine lactam,

2,5-Piperazindion,

alpha,gamma-Diacipiperazine,

Cyclic(glycylglycyl),

Cyclo(glycylglycyl),

Cyclodiglycine

Numbering system

CAS number:106-57-0

MDL number:MFCD00006009

EINECS number:203-411-5

RTECS number:TL6325250

BRN number:112112

PubChem ID:None

Physical property data

1. Character: flake or needle crystal.

2. Density (g/mL, 25℃): Undetermined

3. Relative vapor density (g/mL, air=1): Undetermined

4. Melting point (ºC): 311-312 (decomposition)

5. Boiling point (ºC, normal pressure): Undetermined

6. Boiling point (ºC, kPa): Undetermined

7. Refractive index (D20): Undetermined

8. Flash point (ºC): Undetermined Determined

9. Specific rotation (ºC): Not determined

10. Autoignition point or ignition temperature (ºC): Not determined

11. Vapor Pressure (mmHg, 25ºC): Undetermined

12. Saturated vapor pressure (kPa, 25ºC): Undetermined

13. Heat of combustion (KJ/mol): Undetermined

p>

14. Critical temperature (ºC): Undetermined

15. Critical pressure (KPa): Undetermined

16. Oil-water (octanol/water) partition coefficient Logarithmic value of p>

19. Solubility: soluble in hot water, weakly alkaline.

Toxicological data

1. Acute toxicity: mouse intraperitoneal LD: >500mg/kg;

Ecological data

This substance is toxic to waterSlight harm.

Molecular structure data

1. Molar refractive index: 25.40

2. Molar volume (cm3/mol): 91.5

3. Isotonic specific volume (90.2K ): 227.3

4. Surface tension (dyne/cm): 38.1

5. Dielectric constant:

6. Dipole moment (10-24cm3):

7. Polarizability: 10.07

Compute chemical data

1. Reference value for hydrophobic parameter calculation (XlogP): -1.3

2. Number of hydrogen bond donors: 2

3. Number of hydrogen bond acceptors: 2

p>

4. Number of rotatable chemical bonds: 0

5. Number of tautomers: 6

6. Topological molecule polar surface area 58.2

7. Number of heavy atoms: 8

8. Surface charge: 0

9. Complexity: 116

10. Number of isotope atoms: 0

11. Determine the number of atomic stereocenters: 0

12. Uncertain number of atomic stereocenters: 0

13. Determine the number of chemical bond stereocenters: 0

14. Number of uncertain chemical bond stereocenters: 0

15. Number of covalent bond units: 1

Properties and stability

Avoid contact with strong oxidizing agents.

Storage method

Stored in a cool, ventilated warehouse. Keep away from fire and heat sources. Protect from direct sunlight. The packaging is sealed. should be kept away from oxidizer, do not store together. Equipped with the appropriate variety and quantity of fire equipment. Suitable materials should be available in the storage area to contain spills.

Synthesis method

Originated from the condensation of glycine. Mix glycine and ethylenediamine at a ratio of 1:5, stir and heat, react at 174-176°C for 50 minutes, then place in an icehouse to confirm, filter out the crystals, wash with methanol, and dry to obtain glycyl anhydride. It can also be prepared by condensing glycine in dehydrated glycerol.

Purpose

Used as biochemical reagents. Glycylglycine can be obtained by hydrolysis with alkali, acid or hot water.

This article is from the Internet, does not represent the position of Toluene diisocyanate reproduced please specify the source.https://www.polyether-factory.com/archives/16266

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