Formyl hydrazide

Formyl hydrazide structural formula

Structural formula

Business number 06RG
Molecular formula CH4N2O
Molecular weight 60.06
label

hydrazine formate,

Formic acid hydrazide,

Formic acid hydrazide,

Formic hydrazide,

HCONHNH2

Numbering system

CAS number:624-84-0

MDL number:MFCD00007589

EINECS number:210-867-9

RTECS number:LQ8615000

BRN number:635759

PubChem number:24850161

Physical property data

1. Characteristics: white crystal.

2. Density (g/mL,25/4):

3. Relative vapor density (g/mL,Air=1): Undetermined

4. Melting point (ºC): 55-59

5. Boiling point (ºC,Normal pressure): Undetermined

6. Boiling point (ºC,5.2kPa): Undetermined

7. Refractive Index: Undetermined

8. Flash Point (ºC):>110

9. Specific optical rotation (º): Undetermined

10. Autoignition point or ignition temperature (ºC): Undetermined

11. Vapor pressure (kPa,25ºC): Undetermined

12. Saturated vapor pressure (kPa,60ºC): Undetermined

13. Heat of combustion (KJ/mol): Undetermined

14. Critical temperature (ºC): Undetermined

15. Critical pressure (KPa): Undetermined

16. Oil and water (octanol/Log value of water) partition coefficient: Undetermined

17. Explosion upper limit (%,V/V ): Undetermined

18. Lower explosion limit (%,V/V): Undetermined

19. Solubility: soluble in water.

Toxicological data

1, acute toxicity: mice (peritoneal) LD50: 65mg/kg

Rat (subcutaneous)LD50: 120mg/kg

Since the LD50 of table salt is 3,000 mg/kg, the acute toxicity of BPA is the same as that of table salt.

Ecological data

For products that are slightly harmful to water, do not let large amounts of products come into contact with groundwater, waterways or sewage systems. Do not discharge materials into the surrounding environment without government permission.

Molecular structure data

1. Molar refractive index:13.99

2. Molar Volume (cm3/mol):54.8

3. isotonic ratio (90.2K):137.8

4. Surface Tension (dyne/cm):39.8

5. Polarization Rate10-24cm3): 5.54

Compute chemical data

1. Reference value for hydrophobic parameter calculation (XlogP): None

2. Number of hydrogen bond donors: 2

3. Number of hydrogen bond acceptors: 2

4. Number of rotatable chemical bonds: 0

5. Number of tautomers: 2

6. Topological molecule polar surface area 55.1

7. Number of heavy atoms: 4

8. Surface charge: 0

9. Complexity: 20

10. Number of isotope atoms: 0

11. Determine the number of atomic stereocenters: 0

12. Uncertain number of atomic stereocenters: 0

13. Determine the number of chemical bond stereocenters: 0

14. UnsureNumber of stereocenters of chemical bonds: 0

15. Number of covalent bond units: 1

Properties and stability

Keep away from oxides and moisture.

Storage method

Store in an airtight container in a cool, dry place. The storage place must be away from oxidants and water sources. Avoid contact with moisture and water.

Synthesis method

It is obtained by the reaction of ethyl formate and hydrazine hydrate. Carefully add 85% hydrazine hydrate to the solution of ethyl formate and 95% ethanol, and stir for 10 minutes. When the reaction eases, the reaction solution is heated to reflux for 18 hours, and most of the water and ethanol are evaporated under reduced pressure to obtain crude syrupy product, which is further refined to obtain the finished product of carboxyl hydrazide.

Purpose

Used in organic synthesis.

This article is from the Internet, does not represent the position of Toluene diisocyanate reproduced please specify the source.https://www.polyether-factory.com/archives/19848

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